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Agilent Technologies J&W Biodiesel

Biofuels are becoming more attractive as a viable supplement or alternative to petroleum based fuels. Agilent J&W Biodiesel Capillary GC columns are purposely designed and application-optimised for the analysis of biodiesel to meet ASTM and CEN testing standards.

 
ID (mm)   Length (m)   Film (μm)   Temp Limits (°C)   Part Number  
Biodiesel ASTM D6584 Free/Total Glycerin
0.32  15  0.1  -60 to 400  
123-BD11
Biodiesel EN14105 Free/Total Glycerin
0.32   10  0.1  -60 to 400   
123-BD01
Biodiesel EN14103 FAME Analysis
0.32 30   0.25  40 to 260/270  
1909BD-113
Biodiesel EN14110 Residual Methanol
0.32  30   1.8  20 to 260/280  
123-BD34
 

Biodiesel EN14105 Free/Total Glycerin and Biodiesel ASTM D6584 Free/Total Glycerin

  • Designed for the analysis of free and total glycerin in B100 according to EN14105
    or ASTM D6584
  • Specially processed for extended temperature limit of 400°C
  • High temperature, polyimide-coated fused silica tubing
  • Excellent peak shape and extended column life
  • Bonded and cross-linked
  • Solvent rinsable
  • Retention gaps please order 160-BD65-5 (5m x 0.53 mm)
 

Biodiesel EN14103 FAME Analysis

  • Specially designed for the analysis of esters and linoleic acid methyl esters in B100 using EN14103
  • Bonded and cross-linked
  • Solvent rinsable
 

Biodiesel EN14110 Residual Methanol

  • Specially designed for the determination of trace methanol in B100 using EN14110
  • Bonded and cross-linked
  • Solvent rinsable
 
Biodiesel Test Samples
Description Part Number  
   

Biodiesel MSTFA kit, 10 x 1 mL ampoules,

N-Methyl-N-(trimethylsilyl)trifluoro- acetamide for ASTM method D6584

5190-1407
Biodiesel D6584 kit 2 internal standard solutions, 1 mL, 5/pk and 2 internal standard solutions, 5 mL
5190-1408
Biodiesel E14105 kit, 4 x 1 mL ampoules 4 standard solutions
5190-1409
Biodiesel Monoglyceride kit, 3 x 1 mL ampoules
5190-1410
 

Additionnal Information

EN14105 and ASTM D6584 for the determination of free and total Glycerin
High glycerin content can cause engine deposits, and this is the most important GC method for B100. Agilent’s Biodiesel EN14105 Free/Total Glycerin and Biodiesel ASTM D6584 Free/Total Glycerin GC columns were application-optimized to meet the testing standards.

  • Specially processed for extended temperature limit of 400°C
  • High temperature, polyimide-coated fused silica tubing
  • Excellent peak shape and extended column life

These columns, when combined with Agilent 7890A GC, a high temperature retention gap (Agilent part # 160-BD65-5, 5m x 0.53 mm) and the capillary flow technology Ultimate Union, can provide performance that exceeds EN14105 and D6584 calibration and precision precisions. Retention gap significantly improves peak shape for better accuracy, reproducibility as well as extends column life. The Ultimate Union joins retention gap to column for high temperature, leak free, inert, and easy to use connections.

EN14103 for the determination of ester and linoleic acid methyl ester content
EN14103 is used for the measurement of the proper amount of FAME in B100. Agilent’s Biodiesel EN14103 FAME Analysis GC column provides excellent peak shape for the FAME analysis. When the column is combined with the unsurpassed quantitative precision of Agilent 7890 and 6890 GCs, the Agilent solution provides performance that exceeds the specifications of EN14103.

EN14110 for the determination of methanol content
EN14110 is used for the measurement of residual methanol in B100. High methanol content can raise vapor pressure and increase flammability. Agilent’s Biodiesel EN14110 Residual Methanol GC column was designed for headspace alcohol analysis with excellent peak shape.

EN14331 for the separation and characterization of FAMEs from middle distillate fuels EN14331 ensures the key FAME compounds in the biodiesel are in correct proportion.  However, a complex sample matrix makes this analysis difficult. By leveraging the Capillary Flow Technology Deans Switch for heart cutting 2D GC, a primary HP-5ms column (Agilent part number 19091S-331), and a secondary HP-INNOWax column (Agilent part number 19091N-233), the Agilent solution enables separation of individual FAME compounds from the petroleum hydrocarbons using two dimensional GC without complicated and costly sample preparation. The solution provides a faster and easier approach for full analysis of FAME distribution in biodiesel blends, and exceeds the precision requirements of EN14331.

 

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